The main ingredient is silicon dioxide, which comes from sand, as Tim points out. However there are other ingredients as well.
Glass makers add sodium carbonate, which I believe is so that the glass is easier to form and so that it doesn’t need such high temperatures to manufacture. They also add other metal oxides (aluminium, calcium and magnesium) to make the glass more resistant to chemicals.
There are also various trace compounds, either for stability, or to colour the glass.
Also glass can be made in nature: it can be formed when lightning strikes sand or soil! They are called fulgurites and are hollow glass tubes. They are formed when lightning with a temperature of at least 1,800 °C instantaneously melts the silica and fuses grains together. It can also be formed by volcanic eruptions and meteorite strikes.
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